apicularen-a and ethylene

apicularen-a has been researched along with ethylene* in 1 studies

Other Studies

1 other study(ies) available for apicularen-a and ethylene

Article	Year
Side-chain truncation of apicularen A by olefin cross-metathesis with ethylene. Journal of natural products, 2007, Volume: 70, Issue:8 The three olefinic double bonds of natural apicularen A (1a) were cleaved by olefin cross-metathesis in the presence of ethylene and Hoveyda-Grubbs catalyst with concomitant E/Z isomerization of Delta(17,18). On extended conversion, 18,19-seco-apicularen A (3) was accumulated and isolated in pure state in 25% yield. In total synthesis, 3 is a valuable late-stage intermediate for side-chain-modified apicularens. Topics: Alkenes; Bridged Bicyclo Compounds, Heterocyclic; Ethylenes; Molecular Structure; Stereoisomerism	2007

Article

Year

Side-chain truncation of apicularen A by olefin cross-metathesis with ethylene.

Journal of natural products, 2007, Volume: 70, Issue:8

The three olefinic double bonds of natural apicularen A (1a) were cleaved by olefin cross-metathesis in the presence of ethylene and Hoveyda-Grubbs catalyst with concomitant E/Z isomerization of Delta(17,18). On extended conversion, 18,19-seco-apicularen A (3) was accumulated and isolated in pure state in 25% yield. In total synthesis, 3 is a valuable late-stage intermediate for side-chain-modified apicularens.

Topics: Alkenes; Bridged Bicyclo Compounds, Heterocyclic; Ethylenes; Molecular Structure; Stereoisomerism

2007