antofine has been researched along with propargyl-alcohol* in 1 studies
1 other study(ies) available for antofine and propargyl-alcohol
| Article | Year |
|---|---|
Platinum-catalyzed synthesis of substituted phenanthrenes from biphenyl propargyl alcohols via a carbene intermediate.
An efficient synthesis for phenanthrenes via a Pt-carbene intermediate is described. Using Pt as a catalyst, the readily accessible biphenyl propargyl alcohol substrate can be transformed to the vinylphenanthrene system through a cascade involving electrophilic cyclization, dehydration, and 1,2-H migration. The synthetic utility and efficiency of this protocol were demonstrated via the concise total synthesis of antofine. Topics: Alkynes; Catalysis; Cyclization; Indoles; Methane; Molecular Structure; Phenanthrenes; Phenanthrolines; Platinum Compounds; Propanols | 2014 |