anisomycin has been researched along with decanaldehyde* in 1 studies
1 other study(ies) available for anisomycin and decanaldehyde
| Article | Year |
|---|---|
Three-step synthesis of (±)-preussin from decanal.
A straightforward and stereoselective synthesis of the alkaloid preussin is described starting from decanal and diethyl 3-diazo-2-oxopropylphosphonate. The key steps are an aza-Michael reaction from an α,β-unsaturated diazoketone followed by a highly stereoselective Cu-catalyzed ylide formation and then a [1,2]-Stevens rearrangement. This strategy is feasible for extension to preussin analogues, demonstrating its utility for the rapid construction of all-cis-substituted pyrrolidines. Topics: Aldehydes; Anisomycin; Molecular Structure; Stereoisomerism | 2014 |