anhydrolycorinone and tert-butoxide--potassium

anhydrolycorinone has been researched along with tert-butoxide--potassium* in 1 studies

Other Studies

1 other study(ies) available for anhydrolycorinone and tert-butoxide--potassium

ArticleYear
Intramolecular direct dehydrohalide coupling promoted by KO(t)Bu: total synthesis of Amaryllidaceae alkaloids anhydrolycorinone and oxoassoanine.
    Organic letters, 2012, Sep-07, Volume: 14, Issue:17

    A transition-metal-free intramolecular dehydrohalide coupling via intramolecular homolytic aromatic substitution (HAS) with aryl radicals has been developed in the presence of potassium tert-butoxide and an organic molecule as the catalyst. The methodology has been applied to a concise synthesis of Amaryllidaceae alkaloids viz. oxoassoanine (1b), anhydrolycorinone (1d), and other related structures. Interestingly, the method also works only in the presence of potassium tert-butoxide.

    Topics: Amaryllidaceae Alkaloids; Butanols; Catalysis; Indole Alkaloids; Molecular Structure; Phenanthridines

2012