amphidinolide-c and isoprene

amphidinolide-c has been researched along with isoprene* in 1 studies

Other Studies

1 other study(ies) available for amphidinolide-c and isoprene

Article	Year
A formal synthesis of the C1-C9 fragment of amphidinolide C employing the Tamaru reaction. Organic letters, 2010, Jul-02, Volume: 12, Issue:13 Homoallylation of aldehydes with isoprene and triethylborane catalyzed by Ni(acac)(2) gave hydroxyalkenes in good yield with excellent regio- and stereoselectivity. Cross metathesis of the hydroxyalkenes with methyl acrylate using second-generation Grubbs catalyst and copper(I) iodide afforded alpha,beta-unsaturated esters, which underwent cyclization in the presence of DBU to produce tetrahydrofurans with the correct relative configuration for the C1-C9 fragment of amphidinolides C, C2, and F. Topics: Aldehydes; Boranes; Butadienes; Catalysis; Hemiterpenes; Macrolides; Molecular Structure; Nickel; Organometallic Compounds; Pentanes; Stereoisomerism	2010

Article

Year

A formal synthesis of the C1-C9 fragment of amphidinolide C employing the Tamaru reaction.

Organic letters, 2010, Jul-02, Volume: 12, Issue:13

Homoallylation of aldehydes with isoprene and triethylborane catalyzed by Ni(acac)(2) gave hydroxyalkenes in good yield with excellent regio- and stereoselectivity. Cross metathesis of the hydroxyalkenes with methyl acrylate using second-generation Grubbs catalyst and copper(I) iodide afforded alpha,beta-unsaturated esters, which underwent cyclization in the presence of DBU to produce tetrahydrofurans with the correct relative configuration for the C1-C9 fragment of amphidinolides C, C2, and F.

Topics: Aldehydes; Boranes; Butadienes; Catalysis; Hemiterpenes; Macrolides; Molecular Structure; Nickel; Organometallic Compounds; Pentanes; Stereoisomerism

2010