alpha-cyclodextrin and nitromethane

alpha-cyclodextrin has been researched along with nitromethane* in 1 studies

Other Studies

1 other study(ies) available for alpha-cyclodextrin and nitromethane

ArticleYear
Topography of the 1:1 alpha-cyclodextrin-nitromethane inclusion complex.
    Carbohydrate research, 2000, Feb-11, Volume: 324, Issue:2

    Dissolution of alpha-cyclodextrin (alpha-CD) in 9:1 water-nitromethane smoothly generates the title compound, which crystallizes as the pentahydrate in the orthorhombic space group P2(1)2(1)2(1) with a = 9.452(4), b = 14.299(3), c = 37.380(10) A, and Z = 4. Its crystal structure analysis revealed the alpha-CD macrocycle in an unstrained conformation stabilized through a ring of O-2...O-3' hydrogen bonds between five of the six adjacent glucose residues. The nitromethane is located in the alpha-CD cavity in an orientation parallel to the plane of the macrocycle, and assumes two sites of equal population with the nitro group in excessive thermal motion; the guest is held by van der Waals contacts and C-H...O-type hydrogen bonds to the pyranose H-3 and H-5 protons. The packing of the macrocycles in the crystal lattice is of cage herringbone-type with an extensive intra- and intermolecular hydrogen bonding network. The ready formation of a nitromethane inclusion complex in aqueous nitromethane, and the subtleties of its molecular structure amply demonstrate the ease with which water is expelled from the alpha-CD cavity by a more hydrophobic co-solvent.

    Topics: alpha-Cyclodextrins; Chemical Phenomena; Chemistry, Physical; Cyclodextrins; Hydrogen Bonding; Methane; Models, Molecular; Molecular Structure; Nitroparaffins; Solutions; Solvents; Water

2000