allylsilane and propadiene

allylsilane has been researched along with propadiene* in 1 studies

Other Studies

1 other study(ies) available for allylsilane and propadiene

Article	Year
Enantioselective syntheses of syn- and anti-β-hydroxyallylsilanes via allene hydroboration-aldehyde allylboration reactions. Organic letters, 2011, Apr-15, Volume: 13, Issue:8 The kinetic hydroboration of allenylsilane 5 with ((d)Ipc)(2)BH at -40 °C provides allylborane 9Z with ≥12:1 selectivity. When the hydroboration is performed at temperatures above -40 °C, 9Z isomerizes to the thermodynamically more stable allylborane 9E with >20:1 selectivity. Subsequent treatment of 9Z or 9E with aldehydes at -78 °C provides syn- or anti-β-hydroxyallylsilanes, 7 or 8, respectively. Topics: Aldehydes; Alkadienes; Alkenes; Boron; Hydroxylation; Kinetics; Molecular Structure; Silanes; Stereoisomerism	2011

Article

Year

Enantioselective syntheses of syn- and anti-β-hydroxyallylsilanes via allene hydroboration-aldehyde allylboration reactions.

Organic letters, 2011, Apr-15, Volume: 13, Issue:8

The kinetic hydroboration of allenylsilane 5 with ((d)Ipc)(2)BH at -40 °C provides allylborane 9Z with ≥12:1 selectivity. When the hydroboration is performed at temperatures above -40 °C, 9Z isomerizes to the thermodynamically more stable allylborane 9E with >20:1 selectivity. Subsequent treatment of 9Z or 9E with aldehydes at -78 °C provides syn- or anti-β-hydroxyallylsilanes, 7 or 8, respectively.

Topics: Aldehydes; Alkadienes; Alkenes; Boron; Hydroxylation; Kinetics; Molecular Structure; Silanes; Stereoisomerism

2011