aflatoxin-b and 2-3-dihydrofuran

aflatoxin-b has been researched along with 2-3-dihydrofuran* in 1 studies

Other Studies

1 other study(ies) available for aflatoxin-b and 2-3-dihydrofuran

Article	Year
Short, enantioselective total synthesis of aflatoxin B2 using an asymmetric [3+2]-cycloaddition step. Journal of the American Chemical Society, 2005, Aug-31, Volume: 127, Issue:34 A highly enantioselective [3+2]-cycloaddition reaction of 2,3-dihydrofuran with 1,4-benzoquinones using a chiral oxazaborolidinium triflimidate as catalyst has been developed which allows rapid access to a variety of chiral phenolic tricycles (enantiomeric excesses ranging from 91 to 98%). The utility of this new methodology is demonstrated by a short synthesis of the important pentacyclic natural product, aflatoxin B2. This exploratory study indicates that an even broader application of these catalysts to enantioselective cycloadditions may be possible. Topics: Aflatoxins; Benzoquinones; Cyclization; Furans; Models, Chemical; Stereoisomerism	2005

Article

Year

Short, enantioselective total synthesis of aflatoxin B2 using an asymmetric [3+2]-cycloaddition step.

Journal of the American Chemical Society, 2005, Aug-31, Volume: 127, Issue:34

A highly enantioselective [3+2]-cycloaddition reaction of 2,3-dihydrofuran with 1,4-benzoquinones using a chiral oxazaborolidinium triflimidate as catalyst has been developed which allows rapid access to a variety of chiral phenolic tricycles (enantiomeric excesses ranging from 91 to 98%). The utility of this new methodology is demonstrated by a short synthesis of the important pentacyclic natural product, aflatoxin B2. This exploratory study indicates that an even broader application of these catalysts to enantioselective cycloadditions may be possible.

Topics: Aflatoxins; Benzoquinones; Cyclization; Furans; Models, Chemical; Stereoisomerism

2005