a-201a has been researched along with cyclopentanone* in 1 studies
1 other study(ies) available for a-201a and cyclopentanone
| Article | Year |
|---|---|
An unexpected rearrangement of pent-4-enofuranosides to cyclopentanones upon hydrogenolysis of the anomeric benzyl group.
During our synthesis toward the unique nucleoside antibiotic A201A, we were surprised to find that a benzyl arabino-pent-4-enofuranoside underwent a Ferrier II-like rearrangement readily to provide the corresponding cyclopentanone derivative in high yield and stereoselectivity upon hydrogenolysis of the anomeric benzyl group. Topics: Aminoglycosides; Benzyl Compounds; Cyclopentanes; Glycosides; Hydrogen; Molecular Structure; Stereoisomerism | 2016 |