7-epiclusianone and formic-acid

7-epiclusianone has been researched along with formic-acid* in 1 studies

Other Studies

1 other study(ies) available for 7-epiclusianone and formic-acid

Article	Year
Asymmetric, stereodivergent synthesis of (-)-clusianone utilizing a biomimetic cationic cyclization. Angewandte Chemie (International ed. in English), 2014, Jul-21, Volume: 53, Issue:30 We report a stereodivergent, asymmetric total synthesis of (-)-clusianone in six steps from commercial materials. We implement a challenging cationic cyclization forging a bond between two sterically encumbered quaternary carbon atoms. Mechanistic studies point to the unique ability of formic acid to mediate the cyclization forming the clusianone framework. Topics: Benzophenones; Benzoquinones; Biological Products; Biomimetics; Cations; Cyclization; Formates; Molecular Structure; Stereoisomerism	2014

Article

Year

Asymmetric, stereodivergent synthesis of (-)-clusianone utilizing a biomimetic cationic cyclization.

Angewandte Chemie (International ed. in English), 2014, Jul-21, Volume: 53, Issue:30

We report a stereodivergent, asymmetric total synthesis of (-)-clusianone in six steps from commercial materials. We implement a challenging cationic cyclization forging a bond between two sterically encumbered quaternary carbon atoms. Mechanistic studies point to the unique ability of formic acid to mediate the cyclization forming the clusianone framework.

Topics: Benzophenones; Benzoquinones; Biological Products; Biomimetics; Cations; Cyclization; Formates; Molecular Structure; Stereoisomerism

2014