7-epiclusianone and cyclopropane

7-epiclusianone has been researched along with cyclopropane* in 1 studies

Other Studies

1 other study(ies) available for 7-epiclusianone and cyclopropane

Article	Year
Collective total synthesis of PPAPs: total synthesis of clusianone via intramolecular cyclopropanation. Natural product communications, 2013, Volume: 8, Issue:7 The total synthesis of clusianone was accomplished through the stereoselective construction of a bicyclo[3.3.1]nonane derivative via a three-step sequence, which has been utilized for the total syntheses of nemorosone, garsubellin A, and hyperforin: intramolecular cyclopropanation, formation of a geminal dimethyl group, and regioselective ring opening of cyclopropane. Further elaboration, including chemo- and stereoselective hydrogenation to generate the C7 stereogenic center and cross-metathesis to construct prenyl groups in the side-chains, was employed to complete the total synthesis ofclusianone. Topics: Benzophenones; Benzoquinones; Bridged Bicyclo Compounds; Cyclopropanes; Stereoisomerism	2013

Article

Year

Collective total synthesis of PPAPs: total synthesis of clusianone via intramolecular cyclopropanation.

Natural product communications, 2013, Volume: 8, Issue:7

The total synthesis of clusianone was accomplished through the stereoselective construction of a bicyclo[3.3.1]nonane derivative via a three-step sequence, which has been utilized for the total syntheses of nemorosone, garsubellin A, and hyperforin: intramolecular cyclopropanation, formation of a geminal dimethyl group, and regioselective ring opening of cyclopropane. Further elaboration, including chemo- and stereoselective hydrogenation to generate the C7 stereogenic center and cross-metathesis to construct prenyl groups in the side-chains, was employed to complete the total synthesis ofclusianone.

Topics: Benzophenones; Benzoquinones; Bridged Bicyclo Compounds; Cyclopropanes; Stereoisomerism

2013