5-methyl-2-(3-oxo-1-2-2-trimethylcyclopentyl)benzoquinone has been researched along with propadiene* in 1 studies
1 other study(ies) available for 5-methyl-2-(3-oxo-1-2-2-trimethylcyclopentyl)benzoquinone and propadiene
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Total syntheses of enokipodins A and B utilizing palladium-catalyzed addition of an arylboronic acid to an allene.
The enantioselective total syntheses of enokipodins A and B, alpha-cuparenone-type sesquiterpenoids with antimicrobial activity, have been achieved. The key step is the enantiospecific construction of the quaternary carbon center using a palladium-catalyzed addition of an arylboronic acid to an allene followed by an Eschenmoser-Claisen rearrangement. Topics: Alkadienes; Anti-Bacterial Agents; Antifungal Agents; Biological Products; Boronic Acids; Catalysis; Cyclization; Molecular Structure; Palladium; Sesquiterpenes; Stereoisomerism | 2009 |