5-10-15-20-tetra(4-pyridyl)porphyrin and metaperiodate

5-10-15-20-tetra(4-pyridyl)porphyrin has been researched along with metaperiodate* in 1 studies

Other Studies

1 other study(ies) available for 5-10-15-20-tetra(4-pyridyl)porphyrin and metaperiodate

Article	Year
Polystyrene-bound Mn(T4PyP): a highly efficient and reusable catalyst for biomimetic oxidative decarboxylation of carboxylic acids with sodium periodate. Bioorganic & medicinal chemistry, 2009, May-01, Volume: 17, Issue:9 In this report, highly efficient oxidative decarboxylation of carboxylic acids with sodium periodate catalyzed by a supported manganese(III) porphyrin is described. In the presence of manganese(III) tetra(4-pyridyl)porphyrin supported on cross-linked chloromethylated polystyrene, [Mn(T4PyP)-CMP], as catalyst, carboxylic acids were converted to their corresponding carbonyl compounds via oxidative decarboxylation with sodium periodate using imidazole as axial ligand. The oxidation of anti-inflammatory drugs such Indomethacin and Ibuprofen was carried out successfully and the decarboxylated products were obtained. This catalyst can be reused several times without loss of its catalytic activity in the oxidation reactions. Topics: Biomimetic Materials; Carboxylic Acids; Catalysis; Decarboxylation; Manganese; Metalloporphyrins; Oxidation-Reduction; Periodic Acid; Polystyrenes; Porphyrins	2009

Article

Year

Polystyrene-bound Mn(T4PyP): a highly efficient and reusable catalyst for biomimetic oxidative decarboxylation of carboxylic acids with sodium periodate.

Bioorganic & medicinal chemistry, 2009, May-01, Volume: 17, Issue:9

In this report, highly efficient oxidative decarboxylation of carboxylic acids with sodium periodate catalyzed by a supported manganese(III) porphyrin is described. In the presence of manganese(III) tetra(4-pyridyl)porphyrin supported on cross-linked chloromethylated polystyrene, [Mn(T4PyP)-CMP], as catalyst, carboxylic acids were converted to their corresponding carbonyl compounds via oxidative decarboxylation with sodium periodate using imidazole as axial ligand. The oxidation of anti-inflammatory drugs such Indomethacin and Ibuprofen was carried out successfully and the decarboxylated products were obtained. This catalyst can be reused several times without loss of its catalytic activity in the oxidation reactions.

Topics: Biomimetic Materials; Carboxylic Acids; Catalysis; Decarboxylation; Manganese; Metalloporphyrins; Oxidation-Reduction; Periodic Acid; Polystyrenes; Porphyrins

2009