3-deoxyisoochracinic-acid and phosphine

3-deoxyisoochracinic-acid has been researched along with phosphine* in 1 studies

Other Studies

1 other study(ies) available for 3-deoxyisoochracinic-acid and phosphine

Article	Year
Phosphine/palladium-catalyzed syntheses of alkylidene phthalans, 3-deoxyisoochracinic acid, isoochracinic acid, and isoochracinol. Organic letters, 2012, Jul-06, Volume: 14, Issue:13 In this study we used sequential catalysis-PPh(3)--catalyzed nucleophilic addition followed by Pd(0)-catalyzed Heck cyclization--to construct complex functionalized alkylidene phthalans rapidly, in high yields, and with good stereoselectivities (E/Z ratios of up to 1:22). The scope of this Michael-Heck reaction includes substrates bearing various substituents around the alkylidene phthalan backbone. Applying this efficient sequential catalysis, we accomplished concise total syntheses of 3-deoxyisoochacinic acid, isoochracinic acid, and isoochracinol. Topics: Benzofurans; Catalysis; Molecular Structure; Palladium; Phosphines; Phthalic Acids; Stereoisomerism	2012

Article

Year

Phosphine/palladium-catalyzed syntheses of alkylidene phthalans, 3-deoxyisoochracinic acid, isoochracinic acid, and isoochracinol.

Organic letters, 2012, Jul-06, Volume: 14, Issue:13

In this study we used sequential catalysis-PPh(3)--catalyzed nucleophilic addition followed by Pd(0)-catalyzed Heck cyclization--to construct complex functionalized alkylidene phthalans rapidly, in high yields, and with good stereoselectivities (E/Z ratios of up to 1:22). The scope of this Michael-Heck reaction includes substrates bearing various substituents around the alkylidene phthalan backbone. Applying this efficient sequential catalysis, we accomplished concise total syntheses of 3-deoxyisoochacinic acid, isoochracinic acid, and isoochracinol.

Topics: Benzofurans; Catalysis; Molecular Structure; Palladium; Phosphines; Phthalic Acids; Stereoisomerism

2012