3-6-dichlorocarbazole has been researched along with 1-3-6-8-tetrabromocarbazole* in 2 studies
1 review(s) available for 3-6-dichlorocarbazole and 1-3-6-8-tetrabromocarbazole
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Halogenated indigo dyes: a likely source of 1,3,6,8-tetrabromocarbazole and some other halogenated carbazoles in the environment.
In recent years, a number of halogenated carbazoles have been detected in environmental samples. These emerging contaminants have been shown to be persistent and possess dioxin-like toxicological potential. The goal of this research was to examine the literature to determine likely anthropogenic origin(s) of halogenated carbazoles in the environment. The scientific literature indicated a number of pathways by which 1,3,6,8-tetrabromocarbazole could form in the manufacture of 5,5',7,7'-tetrabromoindigo. The U.S. production history of 5,5',7,7'-tetrabromoindigo correlates well with the concentration rise, decline, and disappearance of 1,3,6,8-tetrabromocarbazole in dated Lake Michigan sediments. Additionally, other halogenated carbazoles that have been found in environmental sediments can be explained by the production of other halogenated indigo dyes. 1,8-dibromo-3,6-dichlorocarbazole can be accounted for by the manufacture of 7,7'-dibromo-5,5'-dichloroindigo, while 1,3,6,8-tetrachlorocarbazole was found at relatively high concentration near the outfall of a U.S. manufacturer of 5,5',7,7'-tetrachloroindigo. Carbazoles containing an iodo-substituent can be explained by the use of iodine as a catalyst in the manufacture of halogenated indigo dyes. 3,6-Dichlorocarbazole measured in soils and dibromocarbazoles measured in more recently deposited sediments are not easily rationalized on the basis of an indigo related source and may be related to other anthropogenic sources or natural origins. Topics: Carbazoles; Coloring Agents; Environment; Environmental Monitoring; Halogenation; Indigo Carmine; Michigan; Polychlorinated Dibenzodioxins; Soil; Soil Pollutants | 2015 |
1 other study(ies) available for 3-6-dichlorocarbazole and 1-3-6-8-tetrabromocarbazole
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Quantitative determination of ultra-trace carbazoles in sediments in the coastal environment.
Carbazole and some of its derivatives may possess dioxin-like toxicity and could be persistent in the environment, but information on their distribution and environmental fate is limited. This study developed and validated an ultra-trace targeted-analysis method for the determination of carbazole, 1,2-benzocarbazole, and 13 halogenated carbazoles in sediments from the river, coast, and North Sea. An 8-g sediment sample was extracted using accelerated solvent extraction combined with in-cell cleanup and analyzed using gas chromatography-tandem mass spectrometry. The method was sensitive and reliable with method detection limits ranging from 4.54 to 52.9 pg/g, and most of the quantification biases and relative standard deviations were <20 and <15%, respectively. Carbazole and 1,2-benzocarbazole were the predominant substances in the sediments (median 565 and 369 pg/g, respectively) followed by 3,6-dichlorocarbazole (median 196 pg/g). The detection frequencies of carbazole, benzo-, 3-chloro-, and 3,6-dichlorocarbazole were >75%, while those of 3,6-dibromo-, 1-bromo-3,6-dichloro-, and 1,8-dibromo-3,6-dichlorocarbazole were approximately 50%. Brominated carbazoles occurred more frequently in marine than river-influenced sediments, which could indicate halogenation after discharge into the river. This is the first study regarding these substances in coastal environments without apparent contamination history. The ubiquity and bioaccumulative potential of these substances needs to be considered. Topics: Carbazoles; Gas Chromatography-Mass Spectrometry; Geologic Sediments; Germany; Halogenation; Limit of Detection; North Sea; Rivers; Seawater; Tandem Mass Spectrometry; Water Pollutants, Chemical | 2016 |