Compounds > 2-5-dideoxy-2-5-imino-d-glucitol

2-5-dideoxy-2-5-imino-d-glucitol and pyrrolidine

2-5-dideoxy-2-5-imino-d-glucitol has been researched along with pyrrolidine* in 1 studies

Other Studies

1 other study(ies) available for 2-5-dideoxy-2-5-imino-d-glucitol and pyrrolidine

Article	Year
Access to pyrrolidine imino sugars via tin(II)-mediated aldol reactions of bislactim ethers: synthesis of 2,5-dideoxy-2,5-imino-D-glucitol. Organic & biomolecular chemistry, 2008, Nov-07, Volume: 6, Issue:21 2,5-Dideoxy-2,5-imino-D-glucitol (DGDP) has been synthesized via the tin(II)-mediated anti-selective aldol reaction of bislactim ether 5 and a 3-O-silylated 2,4-ethylidene-D-erythrose derivative 6. In accordance with density functional theory calculations (at the B3LYP/cc-pVDZ-PP level), pericyclic transition structures with a boat-like conformation and a stabilizing hydrogen bond can account for the unexpected stereoselectivity. Topics: Alcohols; Aldehydes; Ethers; Pyrrolidines; Sorbitol; Stereoisomerism; Tin	2008

Article

Year

Access to pyrrolidine imino sugars via tin(II)-mediated aldol reactions of bislactim ethers: synthesis of 2,5-dideoxy-2,5-imino-D-glucitol.

Organic & biomolecular chemistry, 2008, Nov-07, Volume: 6, Issue:21

2,5-Dideoxy-2,5-imino-D-glucitol (DGDP) has been synthesized via the tin(II)-mediated anti-selective aldol reaction of bislactim ether 5 and a 3-O-silylated 2,4-ethylidene-D-erythrose derivative 6. In accordance with density functional theory calculations (at the B3LYP/cc-pVDZ-PP level), pericyclic transition structures with a boat-like conformation and a stabilizing hydrogen bond can account for the unexpected stereoselectivity.

Topics: Alcohols; Aldehydes; Ethers; Pyrrolidines; Sorbitol; Stereoisomerism; Tin

2008