2-(2-hydroxyethoxy)ethyl-methacrylate and ethylene-dimethacrylate

2-(2-hydroxyethoxy)ethyl-methacrylate has been researched along with ethylene-dimethacrylate* in 2 studies

Other Studies

2 other study(ies) available for 2-(2-hydroxyethoxy)ethyl-methacrylate and ethylene-dimethacrylate

ArticleYear
Polymeric substances for the removal of ochratoxin A from red wine followed by computational modeling of the complexes formed.
    Food chemistry, 2018, Nov-01, Volume: 265

    Ochratoxin A (OTA) is a mycotoxin produced by filamentous-type fungi that contaminates a wide variety of foods and beverages such as wines. In these trials, we evaluated the capacity of the following polymers for the removal of OTA from acidic model solutions and red wine: polyvinylpolypyrrolidone (PVPP), resin of N-vinyl-2-pyrrolidinone with ethylene glycol dimethacrylate and triallyl isocyanurate (PVP-DEGMA-TAIC), and poly(acrylamide-co-ethylene glycol-dimethacrylate) (PA-EGDMA). In acidic model solution, PVP-DEGMA-TAIC and PA-EGDMA polymers removed up to 99.9% of OTA, but their trapping capacity was highly reduced by the presence of competing phenolic substances (i.e. gallic acid and 4-methylcathecol). In real red wine, PA-EGDMA polymer showed the most promising results, with more than 68.0% OTA removal and less than 14.0% reduction in total phenolic. Finally, computational chemistry analyses showed that the affinity between OTA and the polymers studied would be due to Van der Waals interactions.

    Topics: Acrylic Resins; Food Contamination; Methacrylates; Models, Chemical; Ochratoxins; Phenols; Polymers; Povidone; Wine

2018
Effect of the matrix structure and concentration of polymer-immobilized Ni2+-iminodiacetic acid complexes on retention of IgG1.
    Journal of biochemical and biophysical methods, 2006, Apr-30, Volume: 67, Issue:1

    Terpolymer bead particles (100-350 microm in diameter) were prepared by suspension radical polymerization from methacrylate esters [2,3-epoxypropyl methacrylate (GMA), 2-(2-hydroxyethoxy)ethyl methacrylate (DEGMA) and ethylene dimethacrylate (EDMA)] and subsequently derivatized affording iminodiacetic acid (IDA) chelating sorbents. The sorbents differed in pore volumes (0-0.7 cm3/g) and specific surface areas (0.03-9.8 m2/g) of their matrices as well as in the amounts of immobilized Ni2+-IDA complexes (0.03-1.58 mmol/g). The binding of imidazole was studied by frontal chromatography to evaluate the accessibility of Ni2+-IDA complexes. It was found that an increase in the bonded imidazole content with increasing immobilized Ni2+-IDA concentration was strongly dependent on the matrix morphology. A higher pore volume of the matrix significantly improved the utilizability of Ni2+-IDA complexes for imidazole binding. The performance of the sorbents based on two porous matrices with immobilized Ni2+-IDA concentration (0.1-1.58 mmol/g) differing in pore size distributions was compared in immobilized metal affinity chromatography (IMAC) of monoclonal mouse immunoglobulin IgG1 specific against human choriogonadotropic hormone (GTH-spec IgG1). The results have shown that sorbents based on matrix with large pores (up to 20 microm in diameter) exhibited high protein binding capacities. The GTH-spec IgG1 (Mw=158,000) was eluted from all the sorbents in its native form as was confirmed by MALDI-TOF.

    Topics: Animals; Antibodies, Monoclonal; Chelating Agents; Chorionic Gonadotropin; Chromatography, Affinity; Epoxy Compounds; Humans; Imidazoles; Imino Acids; Immunoglobulin G; Methacrylates; Mice; Nickel; Polymers; Porosity; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization

2006