1-butyl-3-methylimidazolium and ferulic-acid

1-butyl-3-methylimidazolium has been researched along with ferulic-acid* in 1 studies

Other Studies

1 other study(ies) available for 1-butyl-3-methylimidazolium and ferulic-acid

ArticleYear
Unraveling the Structural Modifications in Lignin of Arundo donax Linn. during Acid-Enhanced Ionic Liquid Pretreatment.
    Journal of agricultural and food chemistry, 2015, Dec-23, Volume: 63, Issue:50

    Solid acid-enhanced ionic liquid (IL) pretreatment is of paramount importance for boosting the yield of sugars from biomass cost-effectively and environmentally friendly. To unravel the chemical and supramolecular structural changes of lignin after pretreatment, IL-acid lignin (ILAL) and subsequent residual cellulolytic enzyme lignin (RCEL) were isolated from Arundo donax Linn. The structural features were compared with those of the corresponding milled wood lignin (MWL). Results indicated that the pretreatment caused loss of β-O-4', β-β', β-1' linkages and formation of condensed structures in lignin. A preferential breakdown of G-type lignin may have occurred, evidenced by an increased S/G ratio revealed by 2D HSQC NMR analysis. It was determined that the depolymerization of β-O-4' linkage, lignin recondensation, and cleavage of ferulate-lignin ether linkages took place. Moreover, a simulation module was first developed to define morphological changes in lignin based on AFM and TEM analyses. Briefly, tree branch like aggregates was destroyed to monodisperse particles.

    Topics: Acids; Biomass; Carbohydrate Conformation; Coumaric Acids; Imidazoles; Ionic Liquids; Lignin; Magnetic Resonance Spectroscopy; Microscopy, Electron, Transmission; Molecular Structure; Molecular Weight; Poaceae; Spectroscopy, Fourier Transform Infrared; Wood

2015