1-2-azaborine and benzyne

1-2-azaborine has been researched along with benzyne* in 2 studies

Other Studies

2 other study(ies) available for 1-2-azaborine and benzyne

ArticleYear
Superelectrophilicity of 1,2-Azaborine: Formation of Xenon and Carbon Monoxide Adducts.
    Angewandte Chemie (International ed. in English), 2019, 03-18, Volume: 58, Issue:12

    The BN analogue of ortho-benzyne, 1,2-azaborine, is shown to bind carbon monoxide and a xenon atom under matrix isolation conditions, demonstrating its strongly Lewis acidic superelectrophilic nature. The Lewis acid-base complexes involving CO and Xe can be cleaved photochemically and reformed by mildly annealing the matrices. The interaction energy of 1,2-azaborine with Xe is 3 kcal mol

    Topics: Benzene Derivatives; Boron Compounds; Carbon Monoxide; Cycloaddition Reaction; Lewis Bases; Methane; Quantum Theory; Xenon

2019
1,2-Azaborine: The Boron-Nitrogen Derivative of ortho-Benzyne.
    Angewandte Chemie (International ed. in English), 2015, Jun-26, Volume: 54, Issue:27

    The BN analogue of ortho-benzyne, 1,2-azaborine, is generated by flash vacuum pyrolysis, trapped under cryogenic conditions, and studied by direct spectroscopic techniques. The parent BN aryne spontaneously binds N2 and CO2, thus demonstrating its highly reactive nature. The interaction with N2 is photochemically reversible. The CO2 adduct of 1,2-azaborine is a cyclic carbamate which undergoes photocleavage, thus resulting in overall CO2 splitting.

    Topics: Benzene Derivatives; Boron; Boron Compounds; Carbamates; Carbon Dioxide; Models, Molecular; Nitrogen

2015