1-1-diphenyl-2-picrylhydrazyl and stearic-acid

This study investigated the effect of blanching pomegranate seeds (PS) on oil yield, refractive index (RI), yellowness index (YI), conjugated dienes (K232), conjugated trienes (K270), total carotenoid content (TCC), total phenolic compounds (TPC) and DPPH radical scavenging of the extracted oil. Furthermore, phytosterol and fatty acid compositions of the oil extracted under optimum blanching conditions were compared with those from the oil extracted from unblanched PS. Three different blanching temperature levels (80, 90, and 100 °C) were studied at a constant blanching time of 3 min. The blanching time was then increased to 5 min at the established optimum blanching temperature (90 °C). Blanching PS increased oil yield, K232, K270, stigmasterol, punicic acid, TPC and DPPH radical scavenging, whereas YI, β-sitosterol, palmitic acid and linoleic acid were decreased. The RI, TCC, brassicasterol, stearic acid, oleic acid and arachidic acid of the extracted oil were not significantly (

Topics: Antioxidants; Biphenyl Compounds; Carotenoids; Cholestadienols; Dietary Supplements; Eicosanoic Acids; Fatty Acids; Food Technology; Free Radical Scavengers; Linoleic Acid; Linolenic Acids; Oleic Acid; Phenol; Phenols; Phytosterols; Picrates; Plant Oils; Pomegranate; Refractometry; Seeds; Stearic Acids; Temperature

The aim of the study was to identify new potential chemical markers of extra virgin olive oil (EVOO) quality by using a multicomponent analysis approach. Sixty-six EVOOs were purchased from the Italian market and classified according to their price as low price EVOOs (LEVOOs) and high price EVOOs (HEVOOs) costing 3.60-5.90euro/L and 7.49-29.80euro/L respectively. Sensory and chemical parameters strictly related to olive oil quality have been investigated, like volatile substances, polar phenolic substances, antioxidant activity, fatty acid composition, and α-tocopherol. Significant differences in terms of chemical composition and sensory features have been highlighted between the two EVOOs classes investigated, proving a generally lower level of quality of LEVOOs, clearly showed also by means of principal component analysis. Among the most interesting outcomes, R ratio (free tyrosol and hydroxytyrosol over total free and bound forms), measuring the extent of secoiridoids hydrolysis, resulted to be significantly higher in LEVOOs than in HEVOOs. Other key differences were found in the volatile substances composition, in the stearic acid percentage and in p-coumaric acid content.

Topics: Aldehydes; alpha-Tocopherol; Antioxidants; Biphenyl Compounds; Coumaric Acids; Fatty Acids; Food Quality; Humans; Iridoids; Italy; Olea; Olive Oil; Phenols; Picrates; Polyphenols; Stearic Acids; Tocopherols

A new amphiphilic antioxidant (tannyl stearate) derived from reaction of tannic acid with stearic acid was synthesized in order to improve tannic acid solubility in lipid materials. This reaction gives many products having different degree of esterification (tannyl mono, di, tri, tetra, penta, hexa, hepta……stearate) which were separated using silica gel column chromatography and tentative identification was carried out using thin layer chromatography (TLC). The intrinsic viscosities (η) were used to differentiate between the different molecular weight of the produced esters

Topics: Animals; Antioxidants; Biphenyl Compounds; Butylated Hydroxyanisole; Butylated Hydroxytoluene; Emulsifying Agents; Fatty Acids; Free Radical Scavengers; Kidney Function Tests; Liver Function Tests; Mice; Picrates; Rats; Solubility; Stearates; Stearic Acids; Sunflower Oil; Tannins; Viscosity