2,2',2''-terpyridine

Description

2,2',2''-terpyridine, also known as terpy, is a tridentate ligand with three nitrogen atoms that can coordinate to metal ions. It is a versatile ligand that has been extensively studied in coordination chemistry, catalysis, and materials science. Its synthesis is typically achieved through a multi-step process involving the condensation of pyridine with formaldehyde. 2,2',2''-terpyridine forms stable complexes with a wide range of transition metal ions, including ruthenium, iron, and copper. These complexes exhibit interesting photophysical and electrochemical properties, making them attractive for applications in areas such as light-emitting diodes (LEDs), solar cells, and sensors. The coordination of 2,2',2''-terpyridine to metal ions can significantly influence the electronic and steric properties of the resulting complexes. The unique geometry and electronic properties of 2,2',2''-terpyridine allow it to form complexes with diverse structural and functional characteristics. Its ability to form stable and luminescent complexes, particularly with ruthenium, has led to its widespread use in the development of luminescent materials. 2,2',2''-terpyridine has also been explored in supramolecular chemistry for the self-assembly of complex structures, such as metal-organic frameworks (MOFs) and coordination polymers. The rigid structure of 2,2',2''-terpyridine, coupled with its ability to bind to metal ions, makes it a valuable tool for studying the structure and function of metal-containing systems. 2,2',2''-terpyridine is a valuable and versatile compound in various research fields, due to its ability to form stable coordination complexes with a wide range of metal ions, exhibiting diverse electronic and optical properties. This has led to its use in catalysis, supramolecular chemistry, and materials science, among other areas. Its continued study holds promise for advancements in areas such as luminescent materials, sensors, and solar energy.'

2,2',2''-terpyridine: RN given refers to parent cpd [Medical Subject Headings (MeSH), National Library of Medicine, extracted Dec-2023]

2,2':6',2''-terpyridine : A tridentate heterocyclic ligand that binds metals at three meridional sites giving two adjacent 5-membered MN2C2 chelate rings. [Chemical Entities of Biological Interest (ChEBI), Hastings J, Owen G, Dekker A, Ennis M, Kale N, Muthukrishnan V, Turner S, Swainston N, Mendes P, Steinbeck C. (2016). ChEBI in 2016: Improved services and an expanding collection of metabolites. Nucleic Acids Res]